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Title:
Aquatic herbicides
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Having thus described our invention, we claim:
1. A process for improving the activity of aquatic herbicides which comprises applying these herbicides under water to the vegetation to be controlled in the presence of:
A. from 0.005 to 0.2 pounds of a water soluble vinyl addition polymer per gallon of herbicidal solution applied, said water soluble vinyl addition polymer being selected from the group consisting of acrylamide-acrylic acid copolymers, acrylamide-methacrylic acid copolymers, polyacrylic acid, and polymethacrylic acid, said polymer further characterized as having a molecular weight of at least 10,000; and
B. from 0.01-5% by weight of the polymer of an inorganic cross-linking agent from the group consisting of water-soluble trivalent salts of aluminum.
2. The process of claim 1 wherein the water soluble vinyl addition polymer is sodium polyacrylate.
3. The process of claim 1 wherein the inorganic crosslinking agent is selected from the group consisting of sodium aluminate and aluminum chloride.
4. The process of claim 1 wherein the vegetation is Hydrilla.
5. The process of claim 1 wherein the water soluble vinyl addition polymer is contained in a water-in-oil emulsion which can be inverted to cause the solubilization of the polymer when contacted with water.
6. The process of claim 1 wherein the water-soluble vinyl addition polymer is a copolymer of acrylamide and acrylic acid.
7. The process of claim 1 wherein the water-soluble polymer has a molecular weight of at least 1 million.
Other info:
Inventors:
Vartiak, Joseph F. (Naperville, IL, US) Wortley, Jr., George E. (Longwood, FL, US)
Application Number:
825796
Filing Date: 1977-08-18 Publication_date: 1978-10-31 Assignee:
Nalco Chemical Company (Oak Brook, IL)
Primary Class(es):
504/152
504/154, 504/361
Other Classes:
US Patent Ref:
Other Refs:
Other References:
British Pat. 1,056,887, Chem. Abst. vol. 66, (1967) 94152 p. |