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Primary Examiner: Mills, Catherine L.
Assistant Examiner:
Attorney: Premo; John G., Miller; Robert A.

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Title: Aquatic herbicides



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Claims: Having thus described our invention, we claim:

1. A process for improving the activity of aquatic herbicides which comprises applying these herbicides under water to the vegetation to be controlled in the presence of:

A. from 0.005 to 0.2 pounds of a water soluble vinyl addition polymer per gallon of herbicidal solution applied, said water soluble vinyl addition polymer being selected from the group consisting of acrylamide-acrylic acid copolymers, acrylamide-methacrylic acid copolymers, polyacrylic acid, and polymethacrylic acid, said polymer further characterized as having a molecular weight of at least 10,000; and

B. from 0.01-5% by weight of the polymer of an inorganic cross-linking agent from the group consisting of water-soluble trivalent salts of aluminum.

2. The process of claim 1 wherein the water soluble vinyl addition polymer is sodium polyacrylate.

3. The process of claim 1 wherein the inorganic crosslinking agent is selected from the group consisting of sodium aluminate and aluminum chloride.

4. The process of claim 1 wherein the vegetation is Hydrilla.

5. The process of claim 1 wherein the water soluble vinyl addition polymer is contained in a water-in-oil emulsion which can be inverted to cause the solubilization of the polymer when contacted with water.

6. The process of claim 1 wherein the water-soluble vinyl addition polymer is a copolymer of acrylamide and acrylic acid.

7. The process of claim 1 wherein the water-soluble polymer has a molecular weight of at least 1 million.

Other info:


Inventors: Vartiak, Joseph F. (Naperville, IL, US)
Wortley, Jr., George E. (Longwood, FL, US)

Application Number: 825796
Filing Date: 1977-08-18
Publication_date: 1978-10-31
Assignee: Nalco Chemical Company (Oak Brook, IL)
Primary Class(es): 504/152 504/154, 504/361
Other Classes:
US Patent Ref:
3360356Dec, 1967Vartiak71/65.
3393990Jul, 1968Geary71/65.
3959237May, 1976Blank71/93.

Other Refs: 4,810,535
Apr, 1973JP
Other References: British Pat. 1,056,887, Chem. Abst. vol. 66, (1967) 94152 p.