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Primary Examiner: Edmundson, F.C.
Assistant Examiner:
Attorney: Claeboe; B. F., Mueller; Richard P., Kluegel; Arthur E.

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Title: Bright palladium electroplating baths



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Claims: What is claimed is:

1. A stable aqueous electroplating bath, which comprises essentially pure palladium free of alloying elements thereof and being in electrodeposital form, and a Class I brightener selected from the group consisting of methylene bis(naphthalene sodium sulfonate), sodium benzene sulfonate, benzene sulfonamide and phenol-sulfonic acid, and a Class II organic brightener selected from the group consisting of benzaldehyde-o-sodium sulfonate, 2 butyne-1,4-diol, 2 butene-1, 4-diol and allyl sulfonate, and which exhibits a pH value of from 4.5 to 12.

2. An electroplating bath as defined in claim 1, in which there is present 0.1 to 50 grams per liter of palladium and 0.0001 to 25 grams per liter each of a Class I brightener and a Class II organic brightener as set forth.

3. An electroplating bath as defined in claim 1, in which there is also present at least 1 chelating or complexing agent selected from the group consisting of carboxylic and phosphonic chelating agents which is present in an amount from 5 grams per liter up to the solubility limit of the solution.

4. An electroplating bath as defined in claim 1, in which there is included at least one conducting or buffering salt.

5. An electroplating bath as defined in claim 1, wherein the palladium is present in divalent form as an amine complex selected from chloride, bromide, nitrite and sulfite complexes.
Other info:


Inventors: Deuber, John Martin (Nutley, NJ, US)

Application Number: 834349
Filing Date: 1977-09-19
Publication_date: 1978-07-04
Assignee: Oxy Metal Industries Corporation (Warren, MI)
Primary Class(es): 205/265
Other Classes:
US Patent Ref:
3580820May, 1971Yamamura et al.204/43.
3933602Jan, 1976Henzi et al.204/44.
3972787Aug, 1976Nobel et al.204/47.

Other Refs: 7,125,6047,233,178237,8171,143,178
Jul, 1971JP
Aug, 1972JP
Sep, 1945CH
Feb, 1969GB
Other References: Metal Finishing Guide Directory, vol. 42, pp. 358-360, 1974.