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Title: Phenyl thiol carbanilide derivatives, method for the preparation thereof and use thereof as fungicide for agriculture



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Claims: We claim:

1. A compound represented by the formula

where X represents a lower alkylsulfonyl, a lower alkoxycarbonyl, a N-lower alkylcarbamoyl, a lower alkylcarbonyl or an 0,0-di lower alkyl thiophosphonyl, Y represents hydrogen, chlorine, bromine or a lower alkyl, Z represents hydrogen fluorine, chlorine, bromine, a lower alkyl, a lower alkoxy or trifluoromethyl and m represents 1 or 2.

2. The compound according to claim 1 where X is an alkyl sulfonyl having from 1 to 3 carbon atoms, methoxy carbonyl, ethoxy carbonyl, acetyl or 0,0-dimethyl thiophosphonyl, Y is hydrogen or chlorine Z is hydrogen, p-fluorine, p-chlorine, p-bromine or methoxy and m is 1.

3. A fungicidal composition for agriculture comprising 1-95% of a compound of the formula ##STR52## where X represents a lower alkylsulfonyl, a lower alkoxycarbonyl, a N-lower alkylcarbamoyl, a lower alkylcarbonyl or an 0,0-dilower alkyl thiophosphonyl, Y represents hydrogen, chlorine, bromine and a lower alkyl, Z represents hydrogen fluorine, chlorine, bromine, a lower alkyl, a lower alkoxy or trifluoromethyl and m represents 1 or 2, and 99 - 5% (by weight) of adjuvants.

4. The fungicidal composition according to claim 3 wherein X is an alkyl sulfonyl having from 1 to 3 carbon atoms, methoxy carbonyl, ethoxy carbonyl, acetyl or 0,0-dimethylthiophosphonyl, Y is hydrogen or chlorine, Z is hydrogen, p-fluorine, p-chlorine, p-bormine or methoxy and m is 1.

5. A method for killing fungi which harm useful plants or crops characterized by applying to the fungi an effective amount of a compound of the formula ##STR53## where X represents a lower alkylsulfonyl, a lower alkoxycarbonyl, a N-lower alkylcarbamoyl, a lower alkylcarbonyl or an 0,0-di lower alkyl thiophosphonyl, Y represents hydrogen, chlorine, bromine or a lower alkyl, Z represents hydrogen, fluorine, chlorine, bromine, a lower alkyl, a lower alkoxy or trifluorimethyl and m represents 1 or 2.

6. The method according to claim 5 wherein X is an alkyl sulfonyl having from 1 to 3 carbon atoms, methoxy carbonyl, ethoxy carbonyl, acetyl or 0,0-dimethylthiophosphonyl, Y is hydrogen or chlorine, Z is hydrogen, p-fluorine, p-chlorine, p-bromine or methoxy and m is 1.
Other info:


Inventors: Nakagawa, Taizo (Ageo, JA)
Ohmori, Kaoru (Okegawa, JA)
Watanabe, Yutaka (Saitama, JA)
Tejima, Iwao (Ageo, JA)
Ishida, Shuichi (Omiya, JA)
Suzuki, Toshiyuki (Ageo, JA)
Yamada, Osamu (Ageo, JA)

Application Number: 691602
Filing Date: 1976-06-01
Publication_date: 1978-04-25
Assignee: Nippon Kayaku Kabushiki Kaisha (Tokyo, JA)
Primary Class(es): 514/488 514/120, 514/483, 558/58, 558/241, 558/244, 987/212
Other Classes:
US Patent Ref:
3404975Oct, 1968Wilson et al.260/455.
3450745Jun, 1969Payne et al.260/455.
3719702Mar, 1973Traber et al.424/300.
3832374Aug, 1974Liebig et al.260/455.

Other Refs: 1,337,797
Jun, 1962FR

Primary Examiner: Phillips, Delbert R.
Assistant Examiner:
Attorney: Russell & Nields