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Title:
Chromium electroplating baths
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We claim:
1. An aqueous chromium electroplating bath having a pH between 1.8 and 4.9 consisting essentially of water, from 0.05 moles to saturation of ammonia and a water soluble complex of trivalent chromium with (A) glycolic acid, and (B) 0.1 to 3.5 moles of a halide per mole of chromium, said chromium being present in an amount sufficient to provide 0.5 to 3 moles per liter of trivalent chromium.
2. A bath as claimed in claim 1 wherein there is additionally present at least 0.1 moles of borate.
3. A bath as claimed in claim 2 wherein the halide is selected from fluoride and chloride.
4. A bath as claimed in claim 3 additionally containing salts selected from the sulphates, chlorides and fluorides of sodium and potassium.
5. An aqueous chromium electroplating bath having a pH of from 1.8 to 4.9 and consisting essentially of water, from 0.2 to 4 molar ammonium, from 1 to 5 molar of at least one salt selected from the chlorides and sulphates of sodium and potassium and a complex of trivalent chromium with (A) from 0.7 to 3 moles of glycolic acid per mole of chromium and (B) from 0.1 to 1 mole of chloride per mole of trivalent chromium.
Other info:
Inventors:
Crowther, John C. (Stourbridge, EN)
Application Number:
717765
Filing Date: 1976-08-25 Publication_date: 1977-10-11 Assignee:
Albright & Wilson Limited (Warley, EN)
Primary Class(es):
205/286
205/289, 205/290
Other Classes:
US Patent Ref:
Other Refs:
Primary Examiner:
Kaplan, G. L.
Assistant Examiner:
Attorney:
Flynn & Frishauf
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