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Title:
Process for the preparation of dienes and/or trienes
Abstract:
Process for the preparation of dienes and/or trienes comprising reacting a polyolefinically unsaturated compound in the presence of a heterogeneous disproportionation catalyst with a compound according to the general formula ##STR1## wherein R1 and R2, which may be the same or different, each represents an alkyl, aryl, alkaryl or aralkyl group which may or may not contain one or more inert substituents or R1 and R2 form part of a cyclic structure together with the carbon atom to which they are attached. Isononadiene (2,6-dimethyl-1,5-heptadiene) and/or 2,6,10-trimethyl-1,5,9-undecatriene can be obtained by reacting cis-1,4-polyisoprene with isobutene in the presence of a heterogeneous disproportionation catalyst.
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Inventors:
Mulder, Nicolaas (Amsterdam, NL)
Terlouw, Willem (Amsterdam, NL)
Wevers, Jan H. (Amsterdam, NL)
Application Number:
06/399040
Filing Date: 1982-07-16 Publication_date: 1983-10-25 Assignee:
SHELL OIL CO (US)
Primary Class(es):
585/645
585/600, 585/647, 585/646, 585/613
Other Classes:
C07C6/04; C08C19/28; C07C6/00; C08C19/00; C07C6/00
US Patent Ref:
| 3634539 | January, 1972 | Alkema et al. | 585/353 | | | 3637891 | January, 1972 | McGrath et al. | 585/646 | | | 3855338 | December, 1974 | Fitton et al. | 585/647 | PREPARATION OF 6-METHYL-1,5-HEPTADIENE |
Other Refs:
GB1532981| November, 1978 | | | | GB1552368September, 1979 | | | |
Primary Examiner:
Davis, Curtis R.
Assistant Examiner:
Attorney:
Reper, Ronald R.
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