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Title: Exhaust gas sensor having porous, metal-impregnated ceramic element

Abstract: An improved sensor having a ceramic element that undergoes a change in an electrical characteristic in response to a change in the partial pressure of oxygen in a mixture of gases to which the ceramic element is exposed. Sensors of this type are used to detect the air/fuel ratio of mixtures supplied to internal combustion engines. Prior art sensors are characterized by little change in their respective electrical characteristics at low operating temperatures. A charge transfer material, platinum or platinum/rhodium is applied to the ceramic element to facilitate or make possible the electron transfers required for sensor operation at low temperatures. Platinum/rhodium alloy is the currently preferred charge transfer material. This alloy, which preferably is 90% platinum and 10% rhodium, reduces the minimum temperature of operation for the sensor as taught herein, and it also substantially eliminates vaporization loss of the charge transfer material.


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Inventors: Esper, Michael J. (Wayne County, MI, US)
Green, Wells L. (Garden City, MI, US)
Merchant, Stanley R. (Garden City, MI, US)

Application Number: 021374
Filing Date: 1979-03-19
Publication_date: 1980-10-14
Assignee: Ford Motor Company (Dearborn, MI)
Primary Class(es): 422/98 60/276, 324/71.5, 338/22SD, 436/137, 436/151, 502/6
Other Classes:
US Patent Ref:
2782103Feb, 1957Prentiss422/94.
3200011Aug, 1965Baker473/27.
3479257Nov, 1969Shaver422/95.
3564474Feb, 1971Firth et al.422/95.
3645875Feb, 1972Record et al.204/195.
3883307May, 1975Kim252/477.
3992331Nov, 1976Petrow et al.252/472.
4058485Nov, 1977Cheung252/477.
4066413Jan, 1978Segawa et al.422/98.

Other Refs:
Primary Examiner: Marcus, Michael S.
Assistant Examiner:
Attorney: Brown; Robert W., Sadler; Clifford L.