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Title: Manufacture of olefin polymers

Abstract: Manufacture of polymers of .alpha.-monoolefins by polymerization with a Ziegler catalyst system comprising (1) a catalyst component containing titanium and/or vanadium and (2) a particular compound of the metals aluminum, magnesium or zinc. The characteristic feature of the process according to the invention is that the catalyst component (1) containing titanium and/or vanadium is the solid-phase product (VII) contained by first (1.1) bringing a finely divided porous inorganic oxidic material (I), which has the formula Al.sub.2 O.sub.3 or SiO.sub.2.aAl.sub.2 O.sub.3, where a is a number from 0 to 2, into contact with an aluminum compound (II) dissolved in an organic solvent, to form a solid-phase product (III), then (1.2) bringing the solid-phase product (III) obtained in stage (1.1) into contact with a magnesium compound (IV), dissolved in an organic solvent, to form a solid-phase product (V), and finally (1.3) bringing the solid-phase product (V) obtained in stage (1.2) into contact with a compound (VI) of the transition metals titanium and/or vanadium to form a solid-phase product (VII). This process functions better than comparable conventional processes.


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Inventors: Schweier, Guenther (Ludwigshafen, DE, US)
Bachl, Robert (Worms, DE, US)
Mueller-Tamm, Heinz (Ludwigshafen, DE, US)
Frielingsdorf, Hans (Bad Durkheim, DE, US)
Gruber, Wolfgang (Frankenthal, DE, US)
Kolk, Erich (Bad Durkheim, DE, US)

Application Number: 720777
Filing Date: 1976-09-07
Publication_date: 1979-11-20
Assignee: BASF Aktiengesellschaft (DE)
Primary Class(es): 526/124.5 502/103, 526/119, 526/124.6, 526/129, 526/151, 526/153, 526/352
Other Classes:
US Patent Ref:
3718635Feb, 1973Tomoshige et al.526/129.
3787384Jan, 1974Stevens et al.526/156.
3956255May, 1976Ort526/129.

Other Refs: 235215412644161381605
Jun, 1974DE.
Feb, 1972GB.
Jan, 1975GB.

Primary Examiner: Smith, Edward J.
Assistant Examiner:
Attorney: Keil & Witherspoon