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Title:
Manufacture of olefin polymers
Abstract:
Manufacture of polymers of .alpha.-monoolefins by polymerization with a Ziegler catalyst system comprising (1) a catalyst component containing titanium and/or vanadium and (2) a particular compound of the metals aluminum, magnesium or zinc. The characteristic feature of the process according to the invention is that the catalyst component (1) containing titanium and/or vanadium is the solid-phase product (VII) contained by first (1.1) bringing a finely divided porous inorganic oxidic material (I), which has the formula Al.sub.2 O.sub.3 or SiO.sub.2.aAl.sub.2 O.sub.3, where a is a number from 0 to 2, into contact with an aluminum compound (II) dissolved in an organic solvent, to form a solid-phase product (III), then (1.2) bringing the solid-phase product (III) obtained in stage (1.1) into contact with a magnesium compound (IV), dissolved in an organic solvent, to form a solid-phase product (V), and finally (1.3) bringing the solid-phase product (V) obtained in stage (1.2) into contact with a compound (VI) of the transition metals titanium and/or vanadium to form a solid-phase product (VII). This process functions better than comparable conventional processes.
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Inventors:
Schweier, Guenther (Ludwigshafen, DE, US) Bachl, Robert (Worms, DE, US) Mueller-Tamm, Heinz (Ludwigshafen, DE, US) Frielingsdorf, Hans (Bad Durkheim, DE, US) Gruber, Wolfgang (Frankenthal, DE, US) Kolk, Erich (Bad Durkheim, DE, US)
Application Number:
720777
Filing Date: 1976-09-07 Publication_date: 1979-11-20 Assignee:
BASF Aktiengesellschaft (DE)
Primary Class(es):
526/124.5
502/103, 526/119, 526/124.6, 526/129, 526/151, 526/153, 526/352
Other Classes:
US Patent Ref:
| 3718635 | Feb, 1973 | Tomoshige et al. | 526/129. | | 3787384 | Jan, 1974 | Stevens et al. | 526/156. | | 3956255 | May, 1976 | Ort | 526/129. |
Other Refs:
2352154| Jun, 1974 | DE. | | 1264416Feb, 1972 | GB. | | 1381605Jan, 1975 | GB. | | | | | | | |
Primary Examiner:
Smith, Edward J.
Assistant Examiner:
Attorney:
Keil & Witherspoon
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