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Title:
Utilization of dyes for liquid crystal displays
Abstract:
In a cholesteric guest-host liquid crystal composition having a positive dielectric anisotropy and consisting of a nematic host component with a dye incorporated as a guest component therein and an optically active (cholesteric) component, the improvement consisting of a substantially stable and water insoluble azo dye guest component having a pleochroic ratio a.sub.1 /a.sub.2 of at least 6.5 and an absorption maximum in the range of from 350 to 700 nm, said azo dye being a compound of the formula (1) X -- A -- N .dbd. N -- B -- Y (I) wherein A is selected from the group consisting of 1,4-phenylene, 2-hydroxy-1,4-naphthylene and 2-hydroxy-8-amino-1,4-naphthylene; B is selected from the group consisting of 1,4-phenylene, 1,5-naphthylene and 5-substituted benzothiazo-(1,3)-2-yl; X is selected from the group consisting of nitro, nitrile, dimethylamino, di(hydroxyethyl)-amino, phenyl and straight chain C.sub.1 -C.sub.10 alkyl, and Y is a monovalent organic radical that does not promote water solubility in the dye molecule.
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Inventors:
Osman, Maged A. (Zurich, CH) Scheffer, Terry J. (Forch, CH)
Application Number:
809276
Filing Date: 1977-06-23 Publication_date: 1979-01-30 Assignee:
BBC Brown, Boveri & Company, Limited (Baden, CH)
Primary Class(es):
252/299.1
252/299.5
Other Classes:
US Patent Ref:
| 3597044 | Aug, 1971 | Castellano | 252/299. | | 3703329 | Nov, 1972 | Castellano | 252/299. | | 3833287 | Sep, 1974 | Taylor et al. | 252/299. | | 3864022 | Feb, 1975 | Moriyama et al. | 252/299. | | 3960750 | Jun, 1976 | Moriyama et al. | 252/299. | | 3960751 | Jun, 1976 | Moriyama et al. | 252/299. | | 4032219 | Jun, 1977 | Constant et al. | 252/299. | | 4032470 | Jun, 1977 | Bloom et al. | 252/299. | | 4048088 | Sep, 1977 | Yaguchi et al. | 252/299. |
Other Refs:
2627215| Jan, 1977 | DE | | 1459046Dec, 1976 | GB | | | | | | | |
Other References:
White, D. L., et al, J. Appl. Phys., vol. 45, No. 11, pp. 4718-4723 (1974). Blinov, L. M., et al., J. Phys. (Paris), vol. 36, C-1, No. 3, pp. 69-76 (1975). Bloom, A., et al., Mol. Cryst. Liq. Cryst., vol. 40, pp. 213-221 (1977). Bloom, A., et al., Mol. Cryst. Liq. Cryst., vol. 41, pp. 1-4 (Aug. 1977). |