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Title:
Liquid crystal device
Abstract:
Provided is a liquid crystal device comprising a lyotropic-type cholesteric liquid crystal and an enclosure surrounding the liquid crystal, at least a part of which enclosure is transparent, so that the color of the liquid crystal, varying depending upon the change of temperature, is viewable therethrough. The liquid crystal is a concentrated solution having a concentration of approximately 50 to 85 wt.% of a cellulose derivative in water or an organic solvent. The cellulose derivative has an average polymerization degree of 30 to 600 and a chemical structure such that the --OH groups in the cellulose molecule are at least partially substituted with at least one radical of the following formula to the extent that the mole number (M.S.) of a hydroxyalkylating agent bonded with cellulose, per anhydro glucose unit of the cellulose molecule, is 2.0 to 10.0 at average: -- O -- X -- CHR.sub.1 -- CHR.sub.2 -- O ].sub.m H where X is direct bond or --CO--; and, when X is direct bond, R.sub.1 is H or --CH.sub.3, and R.sub.2 is a radical selected from --CH.sub.3, --C.sub.2 H.sub.5, --CH.sub.2 A.sub.1 (A.sub.1 is a radical selected from -OH, halogen, --OCH.sub.3 and --OC.sub.2 H.sub.5) and --CHA.sub.2 --CH.sub.2 A.sub.3 (each of A.sub.2 and A.sub.3 is selected from H, --OH and halogen or both A.sub.2 and A.sub.3 form a double bond together); and when X is --CO--, R.sub.1 is H and R.sub.2 is --CH.sub.3 ; and m is an integer determined depending upon the M.S.
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Inventors:
Maeno, Jun (Sekimachi, JP)
Application Number:
879511
Filing Date: 1978-02-21 Publication_date: 1979-01-02 Assignee:
Hideki Ishii (Tokyo, JP)
Primary Class(es):
349/185
116/216, 250/429, 250/474.1, 252/299.01, 349/199, 374/162, 428/1.5
Other Classes:
US Patent Ref:
| 3114836 | Dec, 1963 | Fergason et al. | 252/408. | | 3410999 | Nov, 1968 | Fergason et al. | 252/408. | | 3529156 | Sep, 1970 | Fergason et al. | 252/408. | | 3594126 | Jul, 1971 | Fergason et al. | 23/230. | | 3666948 | May, 1972 | Mechlowitz et al. | 252/408. | | 3697297 | Oct, 1972 | Churchill et al. | 73/356. | | 3733485 | May, 1973 | Gaynor et al. | 350/351. | | 3796884 | Mar, 1974 | Tricoire | 350/351. | | 3861213 | Jan, 1975 | Parker | 73/356. | | 3936817 | Feb, 1976 | Levy et al. | 350/351. | | 3980300 | Sep, 1976 | Hornsb, Jr. | 428/1. |
Other Refs:
Other References:
Gray, G. W. et al., Liquid Crystals & Plastic Crystals, vol. 1, John Wiley & Sons, Inc., N.Y., pp. 175-198 (1974). Brown, G. H. et al., Liquid Crystals, Gordon & Breach, Science Publishers, N.Y. pp. 147-174 (1967). |