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Title: Phosphating of metallic substrate with electrolytic reduction of nitrate ions

Abstract: In a method for phosphating the surface of a metallic substrate by treament with a phosphating solution comprising nitrite ions as the accelerator, an improvement wherein the supply of the nitrite ions to the phosphating solution is carried out by electrolytic reduction of nitrate ions present in the phosphating solution, whereby a desired concentration of nitrite ions in the phosphating solution is maintained without accumulation of alkali metal and/or ammonium ions unavailable for the phosphating and a uniform phosphate coating film having satisfactorily good coating properties is formed on said surface.


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Inventors: Oka, Shoji (Nara, JP)
Murakami, Ryoichi (Kyoto, JP)
Sueyoshi, Akiko (Osaka, JP)

Application Number: 791470
Filing Date: 1977-04-27
Publication_date: 1978-09-12
Assignee: Nippon Paint Co., Ltd. (Osaka, JP)
Primary Class(es): 148/241 148/262, 204/DIG13, 427/345
Other Classes:
US Patent Ref:
3510412May, 1970Raviv et al.204/103.
3616304Oct, 1971Bedi204/DIG.
3640805Feb, 1972Knight et al.204/DIG.
3996072Dec, 1976Oka et al.148/6.

Other Refs: 2,351,153
Jun, 1974DE

Primary Examiner: Kendall, Ralph S.
Assistant Examiner:
Attorney: Wenderoth, Lind & Ponack