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Title: Aromatic polymers containing a nitrogen-containing ring group, and process for preparation thereof

Abstract: Novel aromatic polymers containing a nitrogen-containing ring group which comprises at least 30 mol% of a recurring unit of the formula ##STR1## Preferably,, the nitrogen-containing ring group ##STR2## is a benzimidazolone, benzimidazolthione, benzimidazole, quinoxalidinedione, benzotriazole, benzothiazolidine, benzothiadiazolidine-S-oxide, benzothiadiazolidine-S-dioxide, benzodithiadiazine, benzodiazophosphole-p-oxide, benzodiazophosphole, benzodiazosilole, or benzodiazoborole ring. These polymers are soluble in various polar solvents. They find a wide range of applications ascribable to these ring groups, for example, as thermally stable resins and permselective membranes. These polymers can be prepared by reacting substantially linear aromatic polymers comprising at least 30 mol% of a recurring unit of the formula ##STR3## with reagents capable of forming 5- or 6-membered nitrogen-containing rings.


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Inventors: Hara, Shigeyoshi (Hino, JA)
Senoo, Masao (Ehime, JA)
Mori, Koh (Hino, JA)
Taketani, Yutaka (Hino, JA)

Application Number: 581933
Filing Date: 1975-05-29
Publication_date: 1978-04-18
Assignee: Teijin Limited (Osaka, JA)
Primary Class(es): 528/171 528/125, 528/172, 528/206, 528/208, 528/210, 528/211, 528/219, 528/271, 528/401, 528/422
Other Classes:
US Patent Ref:
3630994Dec, 1971Culbertson260/49.
3708439Jan, 1973Sayigh et al.260/49.
3920768Nov, 1975Kwiatkowski260/49.

Other Refs:
Primary Examiner: Hoke, V. P.
Assistant Examiner:
Attorney: Sherman & Shalloway