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Title:
Process for producing cationic latexes
Abstract:
A process for producing cationic synthetic rubber latexes by the emulsion polymerization of a conjugated diene or a conjugated diene and a comonomer copolymerizable with the conjugated diene, wherein the polymerization is carried out in the presence of a cationic emulsifier consisting of one or more organic or inorganic acid salts of a .beta.-hydroxy- or .beta.-hydroxymethyl-alkylpolyamine of the general formulae: ##STR1## wherein X is a hydroxyl or hydroxymethyl group, R.sub.1 is a hydrogen atom or an alkyl group of 1 to 20 carbon atoms, R.sub.2 is a hydrogen atom or an alkyl group of 1 to 20 carbon atoms, R.sub.1 + R.sub.2 together contain 8 to 20 carbon atoms, and n is an integer of 1 to 3, an ethylene oxide and/or propylene oxide adduct thereof, or an organic or inorganic acid salt of such an adduct, or a mixture thereof, and in the presence of colloidal alumina.
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Inventors:
Kosaka, Yujiro (Yokohama, JA) Nakazawa, Hideaki (Yokohama, JA) Iikuni, Tetsuo (Shinnanyo, JA) Akashi, Mitsumasa (Shinnanyo, JA)
Application Number:
629445
Filing Date: 1975-11-06 Publication_date: 1977-12-20 Assignee:
Toyo Soda Manufacturing Co., Ltd. (Shinnanyo, JA)
Primary Class(es):
524/724
Other Classes:
US Patent Ref:
| 2700686 | Jan, 1955 | Dickey et al. | 260/584. | | 2887460 | May, 1959 | Dibert et al. | 260/29. | | 3660324 | May, 1972 | Onchi et al. | 260/29. | | 3905932 | Sep, 1975 | Nakazawa et al. | 260/29. | | 3954873 | May, 1976 | Gipson | 260/583. |
Other Refs:
Other References:
Zasshi, J. of the Chemical Society of Japan, Industrial Chem. Section, vol. 68, No. 5, 1965, pp. 956-960. |