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Title:
Polymerization process
Abstract:
An olefine polymerization catalyst includes a complex compound of phosphorus having the general formula ##EQU1## where the various groups are defined. Typical phosphorus compounds include ##EQU2## Catalyst systems containing these phosphorus compounds give a high rate of polymerization together with a low proportion of soluble polymer. The phosphorus compound can be ball-milled with the titanium compound to give an improved effect and the catalyst system may also include an electron donor compound such as triphenylphosphine oxide and tris(dimethylamino)silicon monochloride or a cyclic polyene such as cycloheptatriene.
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Inventors:
Fortuin, Michael Stanley (St. Albans, EN) Caunt, Anthony David (Welwyn Garden City, EN)
Application Number:
416495
Filing Date: 1973-11-16 Publication_date: 1976-08-03 Assignee:
Imperial Chemical Industries Limited (London, EN)
Primary Class(es):
526/77
502/114, 502/115, 502/121, 526/139, 526/159, 526/193, 526/351, 526/352, 558/81, 558/93, 562/878, 564/13, 564/14
Other Classes:
US Patent Ref:
| 3264324 | Aug, 1966 | Gould et al. | 260/347. | | 3415801 | Dec, 1968 | Coover et al. | 260/94. | | 3484424 | Dec, 1969 | Moberly | 260/94. | | 3502634 | Mar, 1970 | Stedefeder et al. | 260/94. | | 3534006 | Oct, 1970 | Kamaishi et al. | 260/93. | | 3558586 | Jan, 1971 | Fodor | 260/93. | | 3629222 | Dec, 1971 | Coover et al. | 260/93. | | 3639375 | Feb, 1972 | Staiger et al. | 260/94. | | 3644320 | Feb, 1972 | Sugiura et al. | 260/93. | | 3701763 | Oct, 1972 | Wada et al. | 260/94. | | 3721721 | Mar, 1973 | Maemoto et al. | 252/431. | | 3752797 | Aug, 1973 | Gordon et al. | 260/94. | | 3766160 | Oct, 1973 | Caunt | 260/94. |
Other Refs:
4,624,246| Jul, 1971 | JA. | | 4,539,621Dec, 1970 | JA. | | 448,516Apr, 1969 | JA. | | 954,071Apr, 1964 | UK. | | 1,002,321Aug, 1965 | UK. | | 1,015,201Dec, 1965 | UK. | | | | | | | |
Other References:
Inorg. Nucl. Chem. Letters vol. 1, (1965), pp. 75-76. Chemical Abstracts, vol. 73, (1970), 77342. Chemical Abstracts, vol. 74, (1971), 87032. |