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Title: Method of preparing resins containing sulfonic acid functionality involving oxidation of thiouronium salts with hydrogen peroxide

Abstract: Resins containing sulfonic acid functionality may be prepared by reacting a chloromethylated polymer matrix with thiourea and then oxidizing the resulting isothiouronium salt to the sulfonic acid in the presence of hydrogen peroxide, either directly or with the intermediate isolation of the thiol.


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Inventors: Clemens, David H. (Willow Grove, PA, US)
Lange, Raymond J. (Wheelersburg, OH, US)

Application Number: 540773
Filing Date: 1975-01-15
Publication_date: 1976-03-16
Assignee: Rohm and Haas Company (Philadelphia, PA)
Primary Class(es): 521/33 521/31
Other Classes:
US Patent Ref:
2559585Feb, 1946Beck et al.260/505.
2868738Jan, 1959Hwa260/2.
3670002Jun, 1972Sheng et al.260/505.

Other Refs:
Primary Examiner: Wong, Jr., Harry
Assistant Examiner: Kulkosky, Peter F.
Attorney: